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(Image: [[https://twitter.com/i/search/https:5C/pbs.twimg.com5C/D5h2dzEWwAAOh_v.jpg5C/5C/media5C]])The first report [5] on the synthesis of Brassinolide appeared a short time after its characterisation, and was followed by a lot of synthetic alternatives which proved that the funtionalization of the rings A and B is an easy task compared to the construction of the side chain, which contains four contiguous chiral centres. The most common starting materials are stigmasterol and ergosterol. Brassicasterol and crinosterol as well as bile acids derivatives and pregnenolone have been also successfully employed in the synthesis of BS.. 

Furla Outlet Five Flyers and four Avalanche are on coach Jon Cooper's squad for the IIHF world championship that opens Friday in Paris and Cologne, Germany."On the two power play units especially, there's one with nearly all Philadelphia players and the other with nearly all Colorado players," defenceman Mike Matheson of the Florida Panthers said this week. "I think the coaches and management have done a good job of finding a group of guys who already have chemistry."That makes a difference in a short tournament."There are also three Winnipeg Jets in goalie Eric Comrie, defenceman Josh Morrissey and centre Mark Scheifele.It may have helped thatCanada's general manager Ron Hextall is also GMin Philadelphia.Canada will be gunning for a third straight world championship gold medal at the 16 team tournament, after topping Finland 2 0 in last year's final and going undefeated in 2015.Theylook to havedrawn the weaker of the two eight team preliminary round groups.They open Friday in Paris against the Czech Republic, followed by clashes with Slovenia, Belarus, France, Switzerland, Norway and Finland.The United States, Sweden and Russiaare in the Cologne based group along with Germany, Latvia, Denmark, Slovakia and Italy.The top four from each group advance to the quarter finals on May 18. The semifinals are on May 20 in Cologne with the final a day later, also in the German city.Canada dominated the Swiss 4 1 in theirlone pre tournament game on Tuesday in Geneva, outshooting them 41 17.  Furla Outlet

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